Syntheses and evaluation of some novel aromatic polyesters. by Clive Paul Bosnyak

Cover of: Syntheses and evaluation of some novel aromatic polyesters. | Clive Paul Bosnyak

Published by University of Birmingham in Birmingham .

Written in English

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Thesis (Ph.D)-University of Birmingham, Dept of Chemistry.

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Open LibraryOL13737886M

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Polyesters are being widely applied in different fields of life due to their excellent characteristics. A book "Polyester" comprises 16 chapters covering synthesis, characterization and applications of polyester.

Chemical and biological methods for synthesis of polyester were one of the most important points of research added. Mechanical, physical, chemical characterizations and. Aromatic polymeric surfac-tants; Ethoxylated aromatic ami-nes; Polyesterification Abstract In this work, three aromatic amines (p-toluidine, p-nitroaniline and p-chloroaniline) were chosen as bases for the repatriation of some nonionic polyesters.

These amines were ethoxy-lated with different total number of ethylene oxide units 6, 12, Novel aromatic polyesters have been synthesized by solution condensation reactions between hydroquinone and 3,4-disubstituted 2,5-thiophenedicarbonyl chlorides. The introduction of phenyl substituents in these poly(p -phenylene 3,4-disubstituted 2,5-thiophendicarboxylate)s did not enhance the fusibility nor the solubility of the resulting Cited by: Novel Aromatic Rigid-rod Comb-like Polyamides and Polyesters Sergei M.

Fomin,* Svetlana A. Makarova, Alla N. Flerova, Anna G. Smolenkova and Eduard N. Teleshov L. Karpov Research Physico-Chemical Institute, Moscow, Russian by: 1.

It describes the preparation, properties and applications of polyesters. Readers will also find details on polyester-based elastomers, biodegradable aliphatic polyester, liquid crystal polyesters and unsaturated polyesters for glass-reinforced composites. Presents an overview of the most recent developments.

Biodegradable Polyesters: Synthesis, Properties, Applications in Book "Biodegradable Polyesters" Stoyko Fakirov (Editor) ISBN: Chapter (PDF Available) May with Reads.

Resolution of water in crude oil emulsion by some novel aromatic amine polyesters Article (PDF Available) in Egyptian Journal of Petroleum 24(3) September with Reads. syntheses. Hardcover – January 1, by No : No Author. 3 Fibres from Partially Aromatic Polyesters.

Early Work Leading to Poly(ethylene Terephthalate). Spread of Polyester Fibre Production. Intermediates. Continuous Polymerisation.

Solid-phase Polymerisation. End-use Development. High-speed Spinning. Ultra-fine Fibres. 4 Other Uses for Semi-aromatic Polyesters. Price: $ Aliphatic polyesters; Aliphatic polyesters have properties similar to those of PE and PP. They are odorless and can be used for trash bags, diapers, and cosmetic and beverage bottles.

They can be processed on conventional processing equipment at °C, in blown and extruded films, foams, and injection moulded products. Aliphatic polyesters C O (CH2)m C O O (CH2)n O x C O C CH3 H O n C O (CH2)5 O n C O C O O CH2 CH2 O n C O C O O (CH2)n O m C O C O O CH2 CH2 O m C O C O O (CH2)n O m C O C O O O n Aliphatic-Aromatic polyesters Fully Aromatic polyesters.

GENERAL CLASSES OF POLYESTERS n: 2 PET. n: 2 PBT. 60 million tons per annum; One third goes for making File Size: 4MB. Polyesters and polyamides remain the most used group of synthetic fibres.

This authoritative book reviews methods of their production, ways of improving their functionality and their wide range of applications. The first part of the book describes raw materials and manufacturing processes, including environmental issues.

Thermal properties of polyesters of p-xylylene glycol, 1,4-cyclohexane - dimethanol, bicyclo[] and [] diols with various diacids 14 Polyesters of trans-1,4-cyclohexanedicarboxylic acid with various diols 15 Tg values and inherent viscosities of polymers prepared from isomers of diethyl.

Hundreds of polyesters exist although only about a dozen are of commercial significance. Polyesters are ubiquitous materials in modern life and are used in diverse applications from drink bottles and photographic film to shirts and fabrics. This book serves as a comprehensive, up-to-date reference and includes the following sections:Price: $   A unsymmetrical and kink non-coplanar heterocyclic dicarboxylic acid monomer, 4-[4-(4-carboxy phenoxy)-naphthyl](4-carboxyphenyl)phthalazinone (3) was successfully synthesized with high purity and high yields.

A series of novel polyamides containing phthalazinone were prepared from the newly synthesized dicarboxylic acid with various Cited by: Aromatic polyamides are high performance materials, having outstanding thermal and mechanical properties.

Poly(2,5-Diamino-terephthalic acid) (PATA) was designed as a novel aromatic polyamide with high strength and modulus. In this paper, 2,5-Diamino-terephthalic acid (DATA), as a monomer of PATA, was synthesized from 2,5-Dimetyl-1,4-phenyldiamine (DPA).Cited by: 1.

Unsaturated and hydroxyl-functionalized C6-dicarboxylic acids were successfully synthesized via olefin metathesis from methyl vinyl glycolate (MVG), a renewable α-hydroxy C4-ester product from Lewis-acid carbohydrate conversion.

Addition of a second-generation Hoveyda–Grubbs catalyst to neat MVG leads to a near quantitative yield of dimethyl-2,5-dihydroxy-3 Cited by: Synthesis and Characterisation of Certain Novel Polyester Elastomers R.

Indira, T. Tamizharuvi, T.V. Rajendran and V. Jaisankar* PG & Research Department of Chemistry, Presidency College (Autonomous), Chennai Received 06 th May ; Revised 15thJuly ; Accepted 18 August ABSTRACTAuthor: R. Indira, T. Tamizharuvi, V. Jaisankar. Tachita Vlad-Bubulac, Corneliu Hamciuc and Oana Petreus, Synthesis and Characterization of Some Polyesters and Poly(ester-imide)s Based on Bisphenol-A Derivatives, High Performance Polymers, 22, 3, (), ().

Then, if these physical properties of MPC polymers improved satisfactorily while maintaining the excellent biocompatibility, novel biocompatible polymer materials could be developed. In these years, we have succeeded in the syntheses of novel diamine and diol monomers containing PC moiety for the preparations of polyamides, polyimides Cited by: 1.

Unsaturated polyesters: Structure and properties, by Boenig, Herman V and a great selection of related books, art and collectibles available now at Novel methods to synthesize aliphatic polyesters of vivid architectures Rajiv K.

Srivastava Department of Fiber and Polymer Technology Royal Institute of Technology Stockholm, Sweden ABSTRACT Cross-linked films of ε-caprolactone (CL) and 1,5-dioxepanone (DXO) havingCited by: 1.

Organic chemistry is a subdiscipline of chemistry that studies the structure, properties and reactions of organic compounds, which contain carbon in covalent bonding. Study of structure determines their chemical composition and of properties includes physical and chemical properties, and evaluation of chemical reactivity to understand their behavior.

A dicarboxylic acid bearing two cinnamic acids units linked in their para positions by a methylene bridge was synthesized by the reaction of 4,4′-methylene-bis(benzaldehyde) and malonic acid, characterized by spectral and elemental analysis and used to prepare a series of novel photocrosslinkable aromatic polyamides through its reaction with various ether-bridged Cited by: 9.

12 MechanismsofAliphatic PolyesterFormation Prof. Andrzej Duda1, Prof. Stanislaw Penczek2 1CenterofMolecularandMacromolecularStudies,PolishAcademyofSciences.

Take a look at our recent peer-reviewed publications or book chapters. Synthesis of Novel Renewable Polyesters and Polyamides with Olefin Metathesis The atom economy is an additional arbitrator in the evaluation of the reaction types. The assessment is illustrated in detail for the case of carbohydrate resources, and.

synthesized aliphatic-co-aromatic co-polyesters [10, 11] to generate biodegradable polymers with satisfactory mechanical properties.

Witt et al [12, 13] showed that the biodegradation rate of co-polyesters made from the aliphatic and aromatic polyesters can be regulated by controlling the composition in aromatic segments. The design and preparation of polymers by using biobased chemicals is regarded as an important strategy towards a sustainable polymer chemistry.

Herein, two aromatic diols, 4-(hydroxymethyl)methoxyphenol and 2-(4-(hydroxymethyl)methoxyphenoxy)ethanol, have been prepared in good yields through the direct reduction of vanillin and hydroxyethylated vanillin (4-(2 Author: Changbo Zhao, Caijuan Huang, Qin Chen, Ian D.

Ingram, Xiankui Zeng, Tianhua Ren, Haibo Xie. Poly(alkylene dicarboxylate)s constitute a family of biodegradable polymers with increasing interest for both commodity and speciality applications. Most of these polymers can be prepared from biobased diols and dicarboxylic acids such as 1,4-butanediol, succinic acid and carbohydrates.

This review provides a current status report concerning synthesis, Cited by: Ring opening polymerization (ROP) of lactones is an interesting technique for the synthesis of polyesters that is currently used for the production of several industrial aliphatic polyesters, i.e.

polyglycolic and polylactic acids, and that has been demonstrated to be also suitable for the synthesis of aromatic polyesters and by: Free Online Library: Evaluation of some conducting polymers as novel antioxidants for rubber vulcanizates.(Research Article, Report) by "International Journal of Polymer Science"; Engineering and manufacturing Oxidation-reduction reaction Observations Oxidation-reduction reactions Polymers Properties Rubber Testing Vulcanization Innovations.

This feature article focuses on a novel strategy towards macrocyclic (co)polyesters that combines controlled ring-opening polymerization of lactones initiated by a cyclic tin(IV) dialkoxide and intramolecular cyclization by photo-cross-linking of pendant unsaturations next to.

polyesters synthesis) are used to illustrate the validity of the proposed framework. In chapter 4, it is found that the bubble column is the potential device for producing unsaturated polyesters by the reactive : Mayankkumar Shah.

Biosynthesis of Aromatic Compounds is a collection of papers from the Proceedings of the Second Meeting of the Federation of European Biochemical Societies in Vienna, on AprilThis volume is based on lectures given at the symposium and covers the studies made on the biosynthesis of aromatic Edition: 1.

The polymer industry is under pressure to mitigate the environmental cost of petrol-based plastics. Biotechnologies contribute to the gradual replacement of petrol-based chemistry and the development of new renewable products, leading to the closure of carbon circle. An array of bio-based building blocks is already available on an industrial scale and is Cited by: Abstract i Abstract Two series of hydroxy-functional hyperbranched polymers based on aliphatic polyesters have been prepared from the 2,2-bis(hydroxymethyl)propionic acid (AB2 monomer) and the di- trimethylolpropane (B4 functional core).

Synthesis of Biodegradable and Biocompostable Polyesters Abstract The main objective of this work was to synthesize linear saturated polyester polyols by polyesterification reaction from dicarboxylic acids and diols. The process conditions were optimized by the temperature profile and also point of vacuum Size: 1MB.

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Full text of "Polyesters: a review of the literature on products of combustion and toxicity" See other formats REFERENCE NBS PUBLICATIONS NAT'L INST. OF STAND & TECH A 1 11 OH 0 3 1 b H 3 NBSIR Polyesters: A Review of the Literature on Products of Combustion and Toxicity Emil Braun and Barbara C.

Levin U S. DEPARTMENT OF COMMERCE National. Preparation and Characterization of Some Aromatic/ Aliphatic Polyamides ham[11] reported that simulated solar radiation of Kevlar 29 aromatic polyamide fabrics in air produced oxidized low- molecular-weight polymers through fission of the amide linkages.

Their results were obtained by proton NMR of the solvent extracts from the polymer samples. Extensively revised and expanded, this timely reference discusses the synthesis, properties, and potential applications of popular and emerging surfactant compounds and systems.

This reference reflects current research trends in green surfactants, the production of surfactants using biotechnological methods, and surfactants based on natural buildinReviews: 1.Chain topology controls many critical properties (e.g., crystallization, solubility, and rheological behavior) of polymeric systems.

The development of linear polyethylene via the Ziegler and Phillips processes in the s provides the most important example, wherein "straightening of the chain" resulted in a rise in T m of ~30°C and significant improvements in strength and .Some Items of Interest to Process R & D Chemists and EngineersCited by: 2.

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